Seawater strontium isotope curve at the Silurian/Devonian boundary: a study of the global Silurian/Devonian boundary stratotype

Present application of ⁸⁷Sr/⁸⁶Sr chemostratigraphy to detailed stratigraphical tasks is limited by inaccurate calibration of the general seawater strontium curve to absolute as well as to relative time scales. For this reason, refinement of the general seawater strontium curve has been suggested, using mainly clearly defined global boundary stratotype sections.

This study reports the first ⁸⁷Sr/⁸⁶Sr data from the global Silurian/Devonian boundary stratotype section and fills an existing 1-Ma gap in available data. Generally, the data from the stratotype fit the range interpolated from published ⁸⁷Sr/⁸⁶Sr data of the general curve, but the slight differences may suggest an existence of a high-order oscillation near the Silurian/Devonian boundary. Higher ⁸⁷Sr/⁸⁶Sr values in the Devonian part of boundary bed 20 (20-beta) may indicate an exotic material influx of recycled sediment.

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